Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand

Bayan A. Faiq; Bayan O. Ahmed

doi:10.21271/ZJPAS.33.5.10

Authors

Bayan A. Faiq Department of Chemistry, Collage of Science, Salahaddin University-Erbil, Kurdistan Region, Iraq.
Bayan O. Ahmed Department of Chemistry, Collage of Science, Salahaddin University-Erbil, Kurdistan Region, Iraq.

DOI:

https://doi.org/10.21271/ZJPAS.33.5.10

Keywords:

Acid hydrazone; complexes; synthesis.

Abstract

Complexes with the general formula [M(LH)₂]X₂ where M=Mn(II),Co(II),Ni(II) and Cu(II) LH= 4-acetylpyridine benzoyl hydrazone and X=chloride ion were synthesized. The structures were confirmed by IR spectroscopy, and characterized by elemental analyses, UV-vis, ¹H.n.m.r ¹³C-n.m.r, and conductivity measurements. Molar conductance values in DMSO indicate that all complexes are electrolytes with mole ratio (1:2) and chloride ions not participate in coordination to central metal ion except Mn complex. The ligand act as bidentate, they coordinates through azomethine nitrogen (>C=N-) and carbonyl oxygen׳s.

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